Fiesta Bowl 1999 (Title Game): Tennessee 23, Florida State 16
Sugar Bowl 2000 (Title Game, VT Big East member): Florida State 46, *Virginia Tech 29
*Sugar Bowl 2001 (In Big East): Miami 37, Florida 20
Orange Bowl 2001 (Title Game): Oklahoma 12, Florida State 2
Orange Bowl 2002: Florida 56, Maryland 23
*Rose Bowl 2002 (Title Game, Big East member): Miami 37, Nebraska 14
Sugar Bowl 2003: Georgia 26, Florida State 13
*Fiesta Bowl 2003 (Title Game, Big East member): Ohio State 31, Miami 24 (2OT)
Orange Bowl 2004 (UM Big East member): Miami 16, Florida State 14
*Fiesta Bowl 2005 (Pitt Big East member): Utah 35, Pittsburgh 7
Sugar Bowl 2005: Auburn 16, Virginia Tech 13
Orange Bowl 2006: Penn State 26, Florida State 23 (3OT)
Orange Bowl 2007: Louisville 24, Wake Forest 13
Orange Bowl 2008: Kansas 24, Virginia Tech 21
Orange Bowl 2009: Virginia Tech 20, Cincinnati 7
Orange Bowl 2010: Iowa 24, Georgia Tech 14
Orange Bowl 2011: Stanford 40, Virginia Tech 12
Sugar Bowl 2012: Michigan 23, Virginia Tech 20 (OT)
Orange Bowl 2012: Clemson -, West Virginia - (Not played yet)
As you can see there were a lot of close games.