I could see Michael Cole (lead WWE announcer and has worked with McAfee for the past year each week, he is a Syracuse Grad). Only issue is Friday night he is in New Orleans for a show so logistics may not work.
Jim Boeheim is the easy one but that is kinda boring honestly. I could see David Muir (part of the ABC/ESPN family), Vanessa Williams, Taye Diggs, Anne Burrell, (does Daniel Baldwin still live here? LOL) would be "celebrity options". To keep it to sports, Carmelo, McNabb or Freeney would also be viable options too.