Not necessarily. Nothing is as cut and dried as you like to believe.
SU - you'd have to replace a legendary HOF coach, and the fans would likely have ridiculously high expectations, and very little patience.
VaTech - he's already more successful than anybody they've had there in ages. Doing the same sorts of things he did at Marquette, only perhaps even better now. Minimal pressure, and he's already considered a success there now. And is paid well.
Clearly, Syracuse is the much better program overall, especially historically.
(However - Past performance is no guarantee of future results.)
But for a new coach coming in, it may not be better than what he's already got.
And especially if the $ isn't better - which, with SU's historically tight wallet, it may not be.